What mass (in g) of urea (CO(NH2)2) in 100.0 g of water is needed to decrease the vapor pressure of water from 55.32 mmHg of pure water to 54.21 mmHg for the solution? The temperature is held constant at 40oC.

Respuesta :

Answer: 6.7 g

Explanation:

As the relative lowering of vapor pressure is directly proportional to the amount of dissolved solute.

The formula for relative lowering of vapor pressure will be,

[tex]\frac{p^o-p_s}{p^o}=\frac{w_2M_1}{w_1M_2}[/tex]

where,

[tex]p^o[/tex] = vapor pressure of pure solvent  (water) = 55.32 mmHg

[tex]p_s[/tex] = vapor pressure of solution = 54.21 mmHg

[tex]w_2[/tex] = mass of solute  (urea) = ? g

[tex]w_1[/tex] = mass of solvent  (water) = 100 g

[tex]M_1[/tex] = molar mass of solvent (water) = 18 g/mole

[tex]M_2[/tex] = molar mass of solute (urea) = 60 g/mole

Now put all the given values in this formula ,we get the vapor pressure of the solution.

[tex]\frac{55.32-54.21}{55.32}=\frac{x\times 18}{100\times 60}[/tex]

[tex]x=6.7g[/tex]

Therefore, 6.7 g of urea is needed in 100.0 g of water is needed to decrease the vapor pressure of water from 55.32 mmHg of pure water to 54.21 mmHg for the solution.